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Scientists discover that the Earth’s atmosphere can clean itself

Researchers have found that a strong electric field between airborne water droplets and surrounding air can create a molecule called hydroxide, which breaks down pollutants.

Amid the constant, disheartening chatter of how climate change is threatening the planet’s survival, here’s a galvanising report to prevent you from falling victim to yet another bout of existential dread.

According to researchers at the University of California, Irvine (UCI), the Earth’s atmosphere can clean itself.

The discovery, which could transform the way we think about air pollution, has been outlined in a paper published in Proceedings of the National Academy of Sciences.

It states that a strong electric field between airborne water droplets and surrounding air can create a molecule called hydroxide (OH) through a previously unknown process.

This unique set of atmospheric conditions is able to facilitate the atmosphere’s self-purification process by neutralising greenhouse gases and chemicals – even in the absence of sunlight.

As explained by Sergey Nizkorodov, a professor of chemistry at UCI, the presence of OH is essential to oxidise hydrocarbons and stop them from accumulating in the atmosphere.

It can also trigger reactions that decompose airborne pollutants and eliminate sulphur dioxide and nitric oxide.

Until recently, it was widely believed that OH is generated via photochemistry or metal catalysts, but the new findings challenge this assumption by proving that it can be created spontaneously.

‘You need OH to oxidize hydrocarbons, otherwise they would build up in the atmosphere indefinitely,’ said Nizkorodov.

‘OH is a key player in the story of atmospheric chemistry. It initiates the reactions that break down airborne pollutants and helps to remove poisonous gases, from the atmosphere.’

To test their hypothesis, Nizkorodov and his team measured OH concentrations in different vials (some containing an air-water surface and others only water) and tracked OH production in darkness by including a ‘probe’ molecule in the vials that fluoresced upon reaction.

As it turns out, OH production rates in darkness are similar to, and in some cases exceed, rates from drivers like sunlight.

The Reaction between Sodium Hydroxide and Atomic Hydrogen in Atmospheric and Flame Chemistry | The Journal of Physical Chemistry A

‘This could change air pollution models quite significantly,’ said Nizkorodov. ‘OH is an important oxidant inside water droplets, and the main assumption in the models is that OH comes from the air.’

However, while this is indeed exciting, it’s important to recognise that further experiments will be necessary to fully understand the implications of the discovery.

Going forward, Nizkorodov and his team will, as a result, perform carefully designed experiments in the real atmosphere in different parts of the world.

Their hope is that we will eventually have a better means of mitigating the air pollution that’s contributing to global warming and one day eradicate it altogether.

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